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101.
在进行能量色散X射线荧光光谱(EDXRF)解谱时,如果给定样品的元素构成,采用纯元素谱图剥离的方式会更加合理,但由于每个元素的谱线都不止一条,如果仅仅针对主线对齐做剥离,会导致结果的严重失真,同时剥离次序对解谱结果有较大影响。介绍了一种最优化算法与纯元素谱剥离相结合的EDXRF解谱方法,该方法以多个纯元素谱的强度大小和峰位漂移道数作为变量构建残差方程,并用最优化计算的方法去调整,直至残差达到极小。实验采用强度顺序剥离、能量顺序剥离和最优化算法拟合3种方法分别对谱线重叠较为严重的La-Ce-Pr-Nd混合液样品的L系谱线进行了解析,结果表明最优化计算方法拟合的谱图与原始谱的残差 (1415.0)比另两种方法(166094.0和3192.7)大幅度缩小,拟合谱与原始谱更为吻合,并且方法在实现时对初值不敏感,解谱精度也不依赖于剥离次序。 相似文献
102.
Perovskite oxides LaCoO_3 prepared by templating, co-precipitation and sol-gel method with different complexants were systematically characterized and its catalytic performances for CO oxidation were investigated. The samples were characterized by X-ray diffraction, thermogravimetry analysis and differential scanning calorimetry, N_2 physisorption, transmission electron microscopy, temperature program reduction of hydrogen, temperature program desorption of oxygen and X-ray photoelectron spectroscopy measurement, results of which show that the properties of LaCoO_3, such as surface morphology, surface area, surface compositions, redox capability, oxygen vacancy, as well as the calcination temperature and formation mechanism, depend intimately on the preparation method. Catalytic tests indicate that the sample prepared by carbon templating method shows the best activity for CO oxidation, with full CO conversion obtained at 135 ℃. In particular, the catalyst can be activated and significant increase of activity can be obtained with the increase of reaction time. The cyclic and longterm stability of catalysts were discussed and compared. 相似文献
103.
The rate of penetration (ROP) model is of great importance in achieving a high efficiency in the complex geological drilling process. In this paper, a novel two-level intelligent modeling method is proposed for the ROP considering the drilling characteristics of data incompleteness, couplings, and strong nonlinearities. Firstly, a piecewise cubic Hermite interpolation method is introduced to complete the lost drilling data. Then, a formation drillability (FD) fusion submodel is established by using Nadaboost extreme learning machine (Nadaboost-ELM) algorithm, and the mutual information method is used to obtain the parameters, strongly correlated with the ROP. Finally, a ROP submodel is established by a neural network with radial basis function optimized by the improved particle swarm optimization (RBFNN-IPSO). This two-level ROP model is applied to a real drilling process and the proposed method shows the best performance in ROP prediction as compared with conventional methods. The proposed ROP model provides the basis for intelligent optimization and control in the complex geological drilling process. 相似文献
104.
This paper focuses on the unconditional stability and convergence of characteristics type methods for the time-dependent incompressible MHD equations. For this purpose, we introduce a new characteristics time-discrete system. The optimal error estimates in and norms for the typical modified characteristics finite element method unconditionally can be deduced, while the whole previous works require certain time-step restrictions. Some numerical experiments document performance of the characteristics type methods for the time-dependent incompressible MHD equations. 相似文献
105.
Wei Xu Ziping Huang Weimin Han Wenbin Chen Cheng Wang 《Computers & Mathematics with Applications》2019,77(10):2596-2607
In this paper numerical approximation of history-dependent hemivariational inequalities with constraint is considered, and corresponding Céa’s type inequality is derived for error estimate. For a viscoelastic contact problem with normal penetration, an optimal order error estimate is obtained for the linear element method. A numerical experiment for the contact problem is reported which provides numerical evidence of the convergence order predicted by the theoretical analysis. 相似文献
106.
This paper is concerned with the inverse problem for non-selfadjoint Sturm–Liouville operator with discontinuity conditions inside a finite interval. Firstly, we give the definitions of generalized weight numbers for this operator which may have the multiple spectrum and then investigate the connections between the generalized weight numbers and other spectral characteristics. Secondly, we obtain the generalized spectral data, which consists of the generalized weight numbers and the spectrum. Then the operator is determined uniquely by the method of spectral mappings. Finally, we give an algorithm for reconstructing the potential function and the coefficients of the boundary conditions and the coefficients of the discontinuity conditions. 相似文献
107.
This paper deals with the determination of an initial condition in degenerate hyperbolic equation from final observations. With the aim of reducing the execution time, this inverse problem is solved using an approach based on double regularization: a Tikhonov’s regularization and regularization in equation by viscose-elasticity. So, we obtain a sequence of weak solutions of degenerate linear viscose-elastic problems. Firstly, we prove the existence and uniqueness of each term of this sequence. Secondly, we prove the convergence of this sequence to the weak solution of the initial problem. Also we present some numerical experiments to show the performance of this approach. 相似文献
108.
Channel estimation is very challenging in millimeter-wave (mmWave) communications since the receiver is usually equipped with a limited number of radio-frequency (RF) chains and a large number of antennas. The receiver can only observe a low-dimensional projection of the received signals due to the huge gap between the numbers of RF chains and antennas. Instead of using the phase-shifter which is not a simple circuit at mmWave, we employ a switch network for analog design, which is equivalent to an antenna selection process. To increase the resolution and accuracy, a nested sampling strategy is used to formulate a virtual array with a larger aperture, aiming to reduce the complexity and power consumption of the system. We also consider the Doppler effect caused by the fast-moving user which may seriously deteriorate the channel estimation accuracy. Based on the covariance fitting criterion, a joint Doppler and channel estimation method is proposed without need of discretizing the angle space, and thus the model mismatch effect can be totally eliminated. Finally, we excavate the temporal variation law of the user to estimate the line-of-sight (LoS) channel in the current time slot by using the estimates from the previous two time slots. Numerical simulation results are provided to demonstrate the effectiveness and superiority of our proposed method. 相似文献
109.
Mohammed Heyouni Farid Saberi-Movahed Azita Tajaddini 《Computers & Mathematics with Applications》2019,77(1):77-92
In the first part of this paper, we investigate the use of Hessenberg-based methods for solving the Sylvester matrix equation . To achieve this goal, the Sylvester form of the global generalized Hessenberg process is presented. Using this process, different methods based on a Petrov–Galerkin or on a minimal norm condition are derived. In the second part, we focus on the SGl-CMRH method which is based on the Sylvester form of the Hessenberg process with pivoting strategy combined with a minimal norm condition. In order to accelerate the SGl-CMRH method, a preconditioned framework of this method is also considered. It includes both fixed and flexible variants of the SGl-CMRH method. Moreover, the connection between the flexible preconditioned SGl-CMRH method and the fixed one is studied and some upper bounds for the residual norm are obtained. In particular, application of the obtained theoretical results is investigated for the special case of solving linear systems of equations with several right-hand sides. Finally, some numerical experiments are given in order to evaluate the effectiveness of the proposed methods. 相似文献
110.
Matti Schneider 《International journal for numerical methods in engineering》2019,118(8):482-494
Building upon the equivalence of the basic scheme in the work of Moulinec and Suquet with gradient descent methods, we investigate the effect of using the celebrated Barzilai-Borwein step size selection technique in this context. We provide an overview of recent convergence theory and present efficient implementations in the context of computational micromechanics, with and without globalization. In contrast to polarization schemes and fast gradient methods, no lower bound on the eigenvalues of the material tangent is necessary for the Barzilai-Borwein scheme. We demonstrate the power of the proposed method for linear elastic and inelastic large scale problems with finite and infinite material contrast. 相似文献